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Phys. Rev. Lett. 99, 188302 (2007) [4 pages]

Slippery or Sticky Boundary Conditions: Control of Wrinkling in Metal-Capped Thin Polymer Films by Selective Adhesion to Substrates

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Hugues Vandeparre1, Julien Léopoldès1, Christophe Poulard1, Sylvain Desprez1, Gwennaelle Derue1, Cyprien Gay2, and Pascal Damman1,*
1Laboratoire de Physicochimie des Polymères, Centre d’Innovation et de Recherche en Matériaux Polymères (CIRMAP), Université de Mons Hainaut, 20, Place du Parc, B-7000 Mons, Belgium
2Centre de recherche Paul-Pascal – CNRS UPR 8641, Université de Bordeaux 1, 115 avenue Schweitzer, F-33600 Pessac, France

Received 22 June 2007; published 31 October 2007

Wrinkling patterns at the metallized surface of thin polymer films are shown to be sensitive to the sticky or slippery character of the polymer-substrate interface. Existing theoretical models were expanded to specific boundary conditions (adhesive versus slippery) in order to rationalize these observations. Based on this concept, we were able to propose a new and simple method to orient the wrinkles by chemically patterning the substrate with regions of high and low adhesion.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.99.188302
DOI:
10.1103/PhysRevLett.99.188302
PACS:
82.35.Gh, 46.32.+x, 68.55.−a

*pascal.damman@umh.ac.be