Active shape-morphing elastomeric colloids in short-pitch cholesteric liquid crystals
Julian S. Evans, Yaoran Sun, Bohdan Senyuk, Patrick Keller, Victor M. Pergamenshchik, Taewoo Lee, and Ivan I. Smalyukh
Accepted
Active elastomeric liquid crystal particles with initial cylindrical shapes are obtained by means of soft lithography and polymerization in a strong magnetic field. Gold nanocrystals infiltrated into these particles mediate energy transfer from laser light to heat, so that the inherent coupling between the temperature-dependent order and shape allows for dynamic morphing of these particles and well-controlled stable shapes. Continuous changes of particle shapes are followed by their spontaneous realignment and transformations of director structures in the surrounding cholesteric host, as well as locomotion in case of a non-reciprocal shape morphing. These findings bridge the fields of liquid crystal solids and active colloids, may enable shape-controlled self-assembly of adaptive composites and light-driven micro-machines, and can be understood by employing simple symmetry considerations along with electrostatic analogies.